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The material is shown to be a mixed phase magnetic system

September 16, 2013

AbstractVariable temperature SQUID magnetometry measurements were made on a sample of commercially available nickel bis 1,5 cyclooctadiene (Ni(COD)2) is reported. The material is shown to be a mixed phase magnetic system where the Ni(COD)2 behaves as a diamagnet containing a paramagnetic component at low temperatures which we believe consists of elemental Ni clusters arising from the decomposition of the material. The magnetic response of the Ni clusters can be described by the combination of two Langevin functions, which indicate cluster magnetic moments of 1.8 B and 15 B suggesting Ni n clusters with n = 2 3 and n = 14 19.

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